[η5-1,3-Bis(trimethylsilyl)cyclopentadienyl]dichlorido[η5-(trimethylsilyl)cyclopentadienyl]titanium(IV)
نویسندگان
چکیده
منابع مشابه
Bis(η5-pentamethylcyclopentadienyl)aluminium tetrabromidoaluminate
The title compound, [Al(C10H15)2][AlBr4], was formed during the reduction of a mixture of Cp*AlBr2 and AlBr3. The Al(III) atoms of the two crystallographically independent cations each lie on an inversion center, and the [AlBr4](-) anions are on general positions. At 123 K, the structure exhibits disorder in two of the Br atoms of the [AlBr4](-) ion, with a ratio occupancy of 0.733 (6): 0.267 (...
متن کاملTricarbonylchlorido(η5-cyclopentadienyl)molybdenum(II)
The structure of the title compound, [Mo(C(5)H(5))Cl(CO)(3)], reveals a pseudo-square-pyramidal piano-stool coordination around the Mo(II) ion, which is surrounded by a cyclo-penta-dienyl ring, three carbonyl groups and a chloride ligand.
متن کاملTricarbonyl(η5-cyclopentadienyl)(trifluorohydroxyborato)tungsten.
The title compound, [W(C(5)H(5))(HOBF(3))(CO)(3)], has a four-legged piano-stool geometry which is typically found for C(5)H(5)W(CO)(3)X complexes. The HOBF(3)(-) anion is the hydrolysis product of BF(4)(-) and is coordinated via oxygen.
متن کاملIodidobis(η5-pentamethylcyclopentadienyl)titanium(III)
In the title complex mol-ecule, [Ti(C(10)H(15))(2)I], the paramagnetic Ti(III) atom is coordinated by two penta-methyl-cyclo-penta-dienyl (Cp*) ligands and one iodide ligand. The two Cp* ligands are in a staggered orientation. The coordination geometry at the titanium atom can be described as distorted trigonal-planar.
متن کاملTris(η5-cyclopentadienyl)hafnium(III)
In the crystal structure of the title compound, [Hf(C(5)H(5))(3)], three cyclo-penta-dienyl ligands surround the Hf(III) atom in a trigonal-planar geometry. The mol-ecule lies on a sixfold inversion axis.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811046228